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Jason M. Keith
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Covalency in Lanthanides. An X-ray Absorption Spectroscopy and Density Functional Theory Study of LnCl6x (x = 3, 2)
MW Löble, JM Keith, AB Altman, SCE Stieber, ER Batista, KS Boland, ...
Journal of the American Chemical Society 137 (7), 2506-2523, 2015
2142015
Determining Relative f and d Orbital Contributions to M–Cl Covalency in MCl62– (M = Ti, Zr, Hf, U) and UOCl5 Using Cl K-Edge X-ray Absorption Spectroscopy …
SG Minasian, JM Keith, ER Batista, KS Boland, DL Clark, SD Conradson, ...
Journal of the American Chemical Society 134 (12), 5586-5597, 2012
2032012
New evidence for 5f covalency in actinocenes determined from carbon K-edge XAS and electronic structure theory
SG Minasian, JM Keith, ER Batista, KS Boland, DL Clark, SA Kozimor, ...
Chemical Science 5 (1), 351-359, 2014
1522014
Energy-degeneracy-driven covalency in actinide bonding
J Su, ER Batista, KS Boland, SE Bone, JA Bradley, SK Cary, DL Clark, ...
Journal of the American Chemical Society 140 (51), 17977-17984, 2018
1272018
A Computational Model Relating Structure and Reactivity in Enantioselective Oxidations of Secondary Alcohols by (−)-Sparteine−PdII Complexes
RJ Nielsen, JM Keith, BM Stoltz, WA Goddard
Journal of the American Chemical Society 126 (25), 7967-7974, 2004
1132004
Pd-mediated activation of molecular oxygen in a nonpolar medium
JM Keith, RJ Nielsen, J Oxgaard, WA Goddard
Journal of the American Chemical Society 127 (38), 13172-13179, 2005
1122005
Mechanism of direct molecular oxygen insertion in a palladium (II)− hydride bond
JM Keith, RP Muller, RA Kemp, KI Goldberg, WA Goddard, J Oxgaard
Inorganic chemistry 45 (24), 9631-9633, 2006
1072006
Quantitative Evidence for Lanthanide-Oxygen Orbital Mixing in CeO2, PrO2, and TbO2
SG Minasian, ER Batista, CH Booth, DL Clark, JM Keith, SA Kozimor, ...
Journal of the American Chemical Society 139 (49), 18052-18064, 2017
942017
Sulfur K-edge X-ray absorption spectroscopy and time-dependent density functional theory of dithiophosphinate extractants: Minor actinide selectivity and electronic structure …
SR Daly, JM Keith, ER Batista, KS Boland, DL Clark, SA Kozimor, ...
Journal of the American Chemical Society 134 (35), 14408-14422, 2012
722012
Covalency in metal–oxygen multiple bonds evaluated using oxygen K-edge spectroscopy and electronic structure theory
SG Minasian, JM Keith, ER Batista, KS Boland, JA Bradley, SR Daly, ...
Journal of the American Chemical Society 135 (5), 1864-1871, 2013
682013
The Osmium–Silicon Triple Bond: Synthesis, Characterization, and Reactivity of an Osmium Silylyne Complex
PG Hayes, Z Xu, C Beddie, JM Keith, MB Hall, TD Tilley
Journal of the American Chemical Society 135 (32), 11780-11783, 2013
652013
Theoretical Examination of the Thermodynamic Factors in the Selective Extraction of Am3+ from Eu3+ by Dithiophosphinic Acids
JM Keith, ER Batista
Inorganic chemistry 51 (1), 13-15, 2012
652012
Pd-mediated activation of molecular oxygen: Pd (0) versus direct insertion
JM Keith, WA Goddard, J Oxgaard
Journal of the American Chemical Society 129 (34), 10361-10369, 2007
652007
The duality of electron localization and covalency in lanthanide and actinide metallocenes
DE Smiles, ER Batista, CH Booth, DL Clark, JM Keith, SA Kozimor, ...
Chemical Science 11 (10), 2796-2809, 2020
522020
Carbon K-Edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory Examination of Metal–Carbon Bonding in Metallocene Dichlorides
SG Minasian, JM Keith, ER Batista, KS Boland, SA Kozimor, RL Martin, ...
Journal of the American Chemical Society 135 (39), 14731-14740, 2013
502013
Validating the biphilic hypothesis of nontrigonal phosphorus (III) compounds
K Lee, AV Blake, A Tanushi, SM McCarthy, D Kim, SM Loria, ...
Angewandte Chemie International Edition 58 (21), 6993-6998, 2019
462019
Mechanism for Activation of Molecular Oxygen by cis- and trans-(Pyridine)2Pd(OAc)H: Pd0 versus Direct Insertion
JM Keith, WA Goddard III
Journal of the American Chemical Society 131 (4), 1416-1425, 2009
462009
Potential Hydrogen Bottleneck in Nickel− Iron Hydrogenase
JM Keith, MB Hall
Inorganic chemistry 49 (14), 6378-6380, 2010
442010
Dehydroalkylative activation of CNN-and PNN-pincer ruthenium catalysts for ester hydrogenation
T He, JC Buttner, EF Reynolds, J Pham, JC Malek, JM Keith, ...
Journal of the American Chemical Society 141 (43), 17404-17413, 2019
422019
Ortho-Metalation Dynamics and Ligand Fluxionality in the Conversion of Os3(CO)10(dppm) to HOs3(CO)8[μ-PhP(C6H421)CH2PPh2]: Experimental …
SH Huang, JM Keith, MB Hall, MG Richmond
Organometallics 29 (18), 4041-4057, 2010
362010
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